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The cysteine sulfenic acid is directly formed from the reactive sulfhydryl moiety of the cysteine side chain with various oxidants. Sulfenic acids (R-SOH) result from the stoichiometric oxidations of thiols with mild oxidants such as H2O2; in solution, however, these derivatives accumulate only transiently due to rapid self-condensation reactions, further oxidations to the sulfinic and/or sulfonic acids, and reactions with nucleophiles such as R-SH. Structural, redox, and mechanistic parameters for cysteine-sulfenic acid function in catalysis and regulation. Juan P. Colomer, Beatriz Fernández de Toro, F. Javier Cañada, Francisco Corzana, Jesús Jiménez Barbero, Ángeles Canales, Oscar Varela. Mengnan Zhang, Tiezheng Jia, Irina K. Sagamanova, Miquel A. Pericás, and Patrick J. Walsh . REACH Reaction mass of Benzene sulfonic acid, hexadecyl(sulfophenoxy)-,disodium salt and Benzene sulfonic acid, - oxibis[hexadecyl]-, disodium salt Soc. Epub 2009 Mar 28. Information. JiaYu Hu, Jiaxin Tian, Kai Wang, Jian Deng. The formation of this derivative in HSA was determined, and the rate constants of its reactions with a reporter disulfide and … Bio-inspired stabilization of sulfenyl iodide RS-I in a Zr( Given the transient nature of sulfenic acids, these addition reactions provide dual purpose. Light-Mediated Sulfenic Acid Generation from Photocaged Cysteine Sulfoxide. Would you like email updates of new search results? Proton transfer in … Vinyl and Aryl Chalcogenides: Sulfur-, Selenium-, and Tellurium-based Functional Groups. m The rate constant of the reaction of H 2 S with the sulfenic acid formed in HSA was determined. Protein sulfenic acid formation: From cellular damage to redox regulation. Organometallic ruthenium anticancer complexes inhibit human peroxiredoxin I activity by binding to and inducing oxidation of its catalytic cysteine residue. Can react with active metals, including iron and aluminum, … Thermo-Responsive Structure and Surface Activity of Kinetically Stabilized Micelle Composed of Fluorinated Alternating Peptides in Organic Solvent. Sulfenic acid chemistry, detection and cellular lifetime. -Unsaturated Sulfenic Acid Esters). Di­lut­ed sul­fu­ric acid re­acts with met­als which are to the left of hy­dro­gen in the row of ac­tiv­i­ty, ac­cord­ing to the gen­er­al scheme: Ме + H₂­SO₄(di­lut­ed) → salt + H₂↑ Markus Griesser, Jean-Philippe R. Chauvin, Derek A. Pratt. TOLUENE SULFONIC ACID, LIQUID, WITH MORE THAN 5% FREE SULFURIC ACID reacts exothermically with chemical bases (for example: amine, amides, and inorganic hydroxides). Turell L, Botti H, Carballal S, Radi R, Alvarez B. J Chromatogr B Analyt Technol Biomed Life Sci. Human serum albumin, the most abundant protein in plasma, possesses a single free thiol. Please enable it to take advantage of the complete set of features! Epub 2006 Oct 24. sulfonic acids Prior art date 1951-04-25 Legal status (The legal status is an assumption and is not a legal conclusion. Evidence for a Morin Type Intramolecular Cyclization of an Alkene with a Phenylsulfenic Acid Group in Neutral Aqueous Solution. Synthesis, Structure, and Reactions of a Sulfenic Acid Bearing a Novel Bowl-Type Substituent:  The First Synthesis of a Stable Sulfenic Acid by Direct Oxidation of a Thiol, Department of Chemistry, Graduate School of Science The University of Tokyo 7-3-1 Hongo, Bunkyo-ku, Tokyo 113, Japan. sulfonic acid (səlfŏn`ĭk), organic compound containing the functional group functional group, in organic chemistry, group of atoms within a molecule that is responsible for certain properties of the molecule and reactions in which it takes part. Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. A careful analysis has led to the determination of the rate constants of the reactions of sulfenic acid with analytical probes and with possible biological targets such as plasma thiols, which lead to mixed disulfides, and hydrogen peroxide, which overoxidizes the sulfenic to sulfinic acid. Access options Buy single article. Kei Goto, Yoko Hino, Takayuki Kawashima*, Masahiro Kaminaga, Emiko Yano, Gaku Yamamoto, Nozomi Takagi, Shigeru Nagase. Kei Goto, Daiju Sonoda, Keiichi Shimada, Shohei Sase, Takayuki Kawashima. Organic sulfonic acids, sodium sulfonates, and alkyl sulfonates were readily reduced to the corresponding disulfides in moderate yields upon treatment with a mixture of a polyphosphoric acid derivative and iodide. Biochimica et Biophysica Acta (BBA) - General Subjects. Cavitands with inwardly and outwardly directed functional groups. http://pubs.acs.org/page/copyright/permissions.html. Density Functional Determination of the Energetics of the Formation of Rose Bengal-photosensitized oxidation of 4-thiothymidine in aqueous medium: evidence for the reaction of the nucleoside with singlet state oxygen. CHEMTRUST, EEB and IPEN comments to SEAC draft opinion on an Annex XV dossier proposing restrictions on Perfluorohexane sulfonic acid (PFHxS) including its ctions salts and related substances . US6207025B1 US09/269,759 US26975999A US6207025B1 US 6207025 B1 US6207025 B1 US 6207025B1 US 26975999 A US26975999 A US 26975999A US 6207025 B1 US6207025 B1 US 6207025B1 Authority US United States Prior art keywords reaction reaction mixture acetic acid … Phosphorus, Sulfur, and Silicon and the Related Elements. Our results support the concept that sulfenic acid is a central intermediate in the formation of oxidized albumin species that … Elucidation of the Mechanism of Reduction of Sulfenic and Selenenic Acids. Sulfonation, in chemistry, any of several methods by which sulfonic acids are prepared. Niroshini M Giles, Aaron B Watts, Gregory I Giles, Fiona H Fry, Jennifer A Littlechild, Claus Jacob. Reactive Sulfur Species: Kinetics and Mechanism of the Hydrolysis of Cysteine Thiosulfinate Ester. Reactions of sulfenic acids with amines, thiols, and thiolates studied by quantum chemical calculations. -1,2-Oxathioles (Cyclic New Insights into the Cystine-Sulfite Reaction. These metrics are regularly updated to reflect usage leading up to the last few days. In hydration level three, the deprotonation reaction certainly occurs. Reviewers, Librarians You’ve supercharged your research process with ACS and Mendeley! NGO reaction to regulatory developments for perfluorohexane sulfonic acid (PFHxS) Download File. Preparation of methane sulfonic acid Download PDF Info Publication number US6207025B1. [1]–[6]. 2018 Nov 30;3(11):16105-16117. doi: 10.1021/acsomega.8b02245. Expired - Lifetime Application number US283765A Inventor Kolling Helmut Current Assignee (The listed assignees may be inaccurate. Reactions of an organoruthenium anticancer complex with 2-mercaptobenzanilide—a model for the active-site cysteine of protein tyrosine phosphatase 1B. Kouji Sasaki, Yuichiro Kondo, Keiji Maruoka. Kazuhiro Ohashi, Kouhei Ito, Tetsuo Iwasawa. Chlorosulfonicacid, also a strong acid. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Albertolle ME, Glass SM, Trefts E, Guengerich FP. However, as a consequence of their strong acidity, their pKa values cannot be measured directly, and values commonly quoted should be regarded as indirect estimates with significant uncertai… 2009. Yumiao Han, Qun Luo, Xiang Hao, Xianchan Li, Fuyi Wang, Wenbing Hu, Kui Wu, Shuang Lü, Peter J. Sadler. Bowen Fan, Yongjun Men, Susan A. P. Rossum, Guotai Li, Rienk Eelkema. Kei Goto, Yusuke Takahashi, Takayuki Kawashima. Modeling of the 5â²-Deiodination of Thyroxine by Iodothyronine Deiodinase: Chemical Corroboration of a Selenenyl Iodide Intermediate. Toshiyuki Saiki, Kei Goto, Renji Okazaki. National Center for Biotechnology Information, Unable to load your collection due to an error, Unable to load your delegates due to an error. In short, these reaction pathways are dependent on the pKa of the sulfenic acid, pH, surrounding thiols, and concentrations. 3 gas or oleum ( eq.-3 ).LAB is synthesized by alkylation of benzene and normal olefins produced brought by petroleum cuts. Steglich M, Lombide R, López I, Portela M, Fló M, Marín M, Alvarez B, Turell L. PLoS One. Also, Cys-SOH can get oxidized to cysteine sulfinic and cysteine sulfonic (cysteic) acid (Scheme 5). Haeri HH, Schunk B, Tomaszewski J, Schimm H, Gelos MJ, Hinderberger D. ChemistryOpen. For the bare reaction we have found two reaction mechanisms, involving proton coupled electron transfer and hydrogen atom transfer processes that produce CH 3 SO 3 and H 2 O. Syntheses and structures of bowl-shaped triarylphosphines and their palladium(II) complexes. Through-space interactions in enshrouded 2020 Oct 12;15(10):e0240580. Your Mendeley pairing has expired. 2,4,6-Trinitrobenzene Sulfonic Acid (TNBSA or TNBS) is a rapid and sensitive assay reagent for the determination of free amino groups.1Primary amines, upon reaction with TNBSA, form a highly chromogenic derivitive, which can be measured at 335 nm (see figure). The dermal LD50 was > 2000 mg/kg body weight (Ciba-Geigy, 1984). New (3) Stockroom Favorite (27) Available on GSA Contract (8) Greener Alternative (4) Application. Redox Chemistry in the Reaction of Oxovanadium(V) with Thiolate-Containing Ligands: the Isolation and Characterization of Non-Oxo Vanadium(IV) Complexes Containing Disulfide and Thioether Groups. Metal-Assisted Oxo Atom Addition to an Fe(III) Thiolate. J Chromatogr B Analyt Technol Biomed Life Sci. Kei Goto, Gaku Yamamoto, Bo Tan, Renji Okazaki. I then need to remove any unreacted TNBS reagent before moving on … Negishi Coupling (1) Suzuki-Miyaura Coupling (3) Stille Coupling (2) Heck Reaction (1) Sonogashira Coupling (2) Buchwald-Hartwig Cross Coupling Reaction (1) Acid-base reactions (12) Alkylations (1) Arylations (1) C-C Bond Formation (1) click chemistry (4) Cross Couplings (2) Grignard Reaction (1) Hiyama Coupling (1) Pegylations (4) Feature. Organometallic ruthenium anticancer complexes inhibit human glutathione-S-transferase π. make sulfonic acids. For permission to reproduce, republish and Our results support the concept that sulfenic acid is a central intermediate in the formation of oxidized albumin species that … Besides, the resulting sulfenic acid exists in two tautomeric forms. Most organic Gloria Villar-Acevedo, Priscilla Lugo-Mas, Maike N. Blakely, Julian A. Rees, Abbie S. Ganas, Erin M. Hanada, Werner Kaminsky, and Julie A. Kovacs . Unusual structures of main group organometallic compounds containing m-terphenyl ligands. Mengnan Zhang, Tiezheng Jia, Haolin Yin, Patrick J. Carroll, Eric J. Schelter, Patrick J. Walsh. Scheme 1: Cysteine oxidation to Cysteine Sulfenic Acid. Epub 2019 Mar 8. Principles in Redox Signaling: From Chemistry to Functional Significance. Metal and Ligand Control of Sulfenate Reactivity: Arene Ruthenium Thiolato-Mono-S-Oxides. Dimedone trapping followed by mass spectrometry analysis confirmed the modification. Ming Li, Guo-Rui Cao, Jing-Wei Zhao, Li-Rong Wen, Yong-Jun Liu, Ya-Mu Xia, Shi-Zheng Zhu. A Comparison between the Acid-Catalysed Reactions of Some Dihydroxamic Acids, Monohydroxamic Acids and Desferal. 2-Propenesulfenic acid, formed from allicin, is thought to be responsible for garlic’s potent antioxidant activity. This article is cited by β-Galactosidase. Self-Interaction of Human Serum Albumin: A Formulation Perspective. Synthesis of Highly Reactive Organosulfur Species using Newly Designed Molecular Cavities. The deprotonated state produced is more stable than the predeprotonated state by 3.72 … Abu Bin Ihsan, Yasuhito Koyama, Toshiaki Taira, Tomohiro Imura. The next water molecules entering the matrix are more weakly bound and able to solvate the protons, and the final stage is bulk water filled in the open pore structure. Quantification of bindings of organometallic ruthenium complexes to GSTπ by mass spectrometry. tert-Butyl Phenyl Sulfoxide: A Traceless Sulfenate Anion Precatalyst. Chem. In these reactions, formation of mixed anhydrides each having a P–O–S linkage is the key step, and subsequent attack of iodide on the sulfur atom gives the corresponding sulfonyl iodides which are reduced further exothermally to the disulfides with hydrogen iodide. Syntheses and Structural Characterizations of a Novel Bowl-Type Germanol and Its Derivatives. Sulfuric acid (American / IUPAC spelling) or sulphuric acid (traditional / British spelling), also known as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with molecular formula H 2 SO 4.It is a colourless and viscous liquid that is soluble in water and is synthesized in reactions that are highly exothermic. Dorota Krasowska, Luca Sancineto, Małgorzata Deska, Józef Drabowicz. Mengnan Zhang, Tiezheng Jia, Carol Y. Wang, and Patrick J. Walsh . A highly chemoselective Mukaiyama aldol reaction of saturated aldehyde over unsaturated aldehyde with enol tris(2,6-diphenylbenzyl)silyl ether. Self-Folded Silyl Cavitands with In- and Outwardly Directed Allyl Groups. Kei Goto, Michel Holler, and ; Renji Okazaki; View Author Information. Autopsy revealed no unusual findings. sulfonic acid moieties are less acidic but more hydrophobic than arene-SO3H species, leading to superior overall activities for water-mediated acid-catalyzed organic reactions. However, its properties are poorly understood. In contrast, oxidations of cysteinyl side chains in proteins, where disulfide bond formation can … Mass spectrometry with a DART ion sourcewere used to identify 2-propenes… Functions in Oxygen Atom Transfer and Catalytic Oxidation of PPh3 to O═PPh3 by Molecular O2. Epub 2018 Nov 28. Dissolution in water or dilution of concentrated solutions with water may generate significant heat. The thiol of albumin is oxidized by hydrogen peroxide and peroxynitrite to a relatively stable sulfenic acid, which can be detected through different strategies including reduction with sodium arsenite and reaction with glutathione. Department of Chemistry, Graduate School of Science The University of Tokyo 7-3-1 Hongo, Bunkyo-ku, Tokyo 113, Japan . Like sulfuric acid, sulfonic acids are highly corrosive, they react vigorously with water, and can cause skin burns. Kei Goto, Michel Holler, Gaku Yamamoto, Renji Okazaki. The rate constant of the reaction of H2S with the sulfenic acid formed in HSA was determined. Second, they are useful reactions for the synthesis of desired sulfoxides. Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Howard Hughes Medical Institute/United States. The Case of Substrate-Inhibited Catalysis. sulfonic acid (səlfŏn`ĭk), organic compound containing the functional group functional group, in organic chemistry, group of atoms within a molecule that is responsible for certain properties of the molecule and reactions in which it takes part. Sulfonation is a difficult reaction to perform on an industrial scale because the reaction is rapid and highly exothermic, releasing approximately 380 kJ/kg SO3 (800 BTUs per pound of SO3) reacted[2]. Eileen Y. Sneeden, Mark J. Hackett, Julien J. H. Cotelesage, Roger C. Prince, Monica Barney, Kei Goto, Eric Block, Ingrid J. Pickering, and Graham N. George . Filipovic MR, Zivanovic J, Alvarez B, Banerjee R. Chem Rev. Hydroxylamine-O-sulfonic acid ("HOSA") is the inorganic compound with molecular formula H 3 NO 4 S that is formed by the sulfonation of hydroxylamine with oleum.It is a white, water-soluble and hygroscopic, solid, commonly represented by the condensed structural formula H 2 NOSO 3 H, though it actually exists as a zwitterion and thus is more accurately represented as + H 3 NOSO 3 −. Bo Tan, Kei Goto, Junji Kobayashi, Renji Okazaki. This derivative has been previously detected and quantified. The reactions can generate dangerously large amounts of heat in small spaces. Alan C. Spivey, Jacqueline Colley, Lindsey Sprigens, Susan M. Hancock, D. Stuart Cameron, Kordi I. Chigboh, Gemma Veitch, Christopher S. Frampton, Harry Adams. The reaction of thiols with H 2 O 2 is central to many processes essential to life, from protein folding to redox signaling. Transnitrosation from a stable thionitrate to an amine with concomitant formation of a sulfenic acid. In 1746 in Birmingham, England, John Roebuck began producing sulfuric acid in lead-lined chambers, which were stronger and less expensive, and could be made much larger, than the glass containers which had been used previously. Novel Intramolecular Cyclization Reaction Involving a Thionitroso Group: Formation of a 3,3a-Dihydro-2,1-benzisothiazole from an o-Alkylthionitrosoarene. Tetsuo Iwasawa, Yoshiki Nishimoto, Kento Hama, Toshinori Kamei, Masaki Nishiuchi, Yasuhiko Kawamura. A Cyclochiral Conformational Motif Constructed Using a Robust Hydrogen-Bonding Network. Sulfuric acid, H 2 SO 4. Sulfonic acids are organic analogs of sulfuric acid, an inorganic compound that is a very strong acid. Formation of a Stable Sulfenic Acid by Hydrolysis of a Thionitrate and a Sulfenyl Bromide. A reaction analysis for deprotonation of the sulfonic group in a model molecule of perfluorosulfonic acid (PFSA) at low hydration levels was performed. without permission from the American Chemical Society. (2,4,6-Trinitrobenzene Sulfonic Acid) TS-28997 Product Description Number TS-28997 Introduction 2,4,6-Trinitrobenzene Sulfonic Acid (TNBSA or TNBS) is a rapid and sensitive assay reagent for the determination of free amino groups.1 Primary amines, upon reaction with TNBSA, form a highly chromogenic derivitive, which can be measured at 335 nm (see figure). E. coli Expression, purification and initial characterization of human serum albumin domain I and its cysteine 34. Curcumin-based sulfenic acid as a light switch for the binding of biothiols. A novel dendrimer-type m-terphenyl substituent for the kinetic stabilization of highly reactive species. Reacts with sodium hypochlorite to produce … PFSA is usually adopted as a polymer electrolyte membrane in polymer electrolyte fuel cells. Protein sulfenic acids (R-SOH) are receiving increased interest as intermediates in redox processes. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. H Bulletin of the Chemical Society of Japan 2003 , 76 (2) , 283-290. In addition, H2S is able to react with sulfenic acids (RSOH). The gas phase reaction between methane sulfonic acid (CH 3 SO 3 H; MSA) and the hydroxyl radical (HO), without and with a water molecule, was investigated with DFT-B3LYP and CCSD(T)-F12 methods. Mahmuda Nargis, Abu Bin Ihsan, Yasuhito Koyama. Yu Lin, Yongdong Huang, Wei Zheng, Fuyi Wang, Abraha Habtemariam, Qun Luo, Xianchan Li, Kui Wu, Peter J. Sadler, Shaoxiang Xiong. Yuko Ikeda, Yuta Sakaki, Yoritaka Yasuda, Preeyanuch Junkong, Takumi Ohashi, Kosuke Miyaji. Al Claiborne, T Conn Mallett, Joanne I Yeh, James Luba, Derek Parsonage. Hua-Fen Hsu, Chia-Ling Su, Neeruganti O. Gopal, Chi-Chin Wu, Wei-Cheng Chu, Yi-Fang Tsai, Ya-Ho Chang, Yi-Hung Liu, Ting-Shen Kuo, Shyue-Chu Ke. Preparation of methane sulfonic acid Download PDF Info Publication number US6207025B1. Furthermore, two sulfenic acids can form thiosulfinate and/or thiosulfonate (Scheme 3) or can result in sulfinic acid and cysteine (Scheme 4). Types: Response. Synthesis, Structure, and Reactivities of a Stable Primary-alkyl-substituted Sulfenic Acid. Hypervalent Derivatives of Selenium and Tellurium. This site needs JavaScript to work properly. Isotopic tagging of oxidized and reduced cysteines (iTORC) for detecting and quantifying sulfenic acids, disulfides, and free thiols in cells. Chemistry and Catalysis in Functional Cavitands. This chapter explores the reactions of carboxylic, phosphoric, and sulfonic acids and their derivatives. Electronic Supporting Information files are available without a subscription to ACS Web Editions. Synthesis, 13C NMR, and UV spectroscopic study of 13C-labeled nitrile N-oxide. Bolaamphiphilic properties and pH-dependent micellization of quercetin polyglycoside. They are typically unstable and decay mainly through reaction with a second thiol to form disulfides. not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information Jinyang Li, Eunkyoung Kim, Kelsey M. Gray, Christina Conrad, Chen‐Yu Tsao, Sally P. Wang, Guanghui Zong, Giuliano Scarcelli, Kimberly M. Stroka, Lai‐Xi Wang, William E. Bentley, Gregory F. Payne. Soluble metal oxides and hydroxides are called alkalis, and react with acids in solution. John J. Tanner, Zachary D. Parsons, Andrea H. Cummings, Haiying Zhou, Kent S. Gates. Most metal oxides are insoluble solids. Note: Carballal S, Alvarez B, Turell L, Botti H, Freeman BA, Radi R. Amino Acids. Please reconnect, Authors & Kazumasa Oya, Hidetake Seino, Midori Akiizumi, and Yasushi Mizobe . Synthesis of the functionalized cavitands with inwardly directed dialkylsilyl groups and phosphorous lone pairs. Bulletin of the Chemical Society of Japan. 2009 Apr;42(4):305-11. doi: 10.1590/s0100-879x2009000400001. Dissolution in water or dilution of concentrated solutions with water may generate heat. Electrophilic Activation of Oxidized Sulfur Ligands and Implications for the Biological Activity of Ruthenium(II) Arene Anticancer Complexes. Isolierung und röntgenstrukturanalytische Charakterisierung einer stabilen Selenensäure. The initial products are assumed to be sulfenic acids, but their observation, and the kinetic and mechanistic characterization of their subsequent reactions, has proven challenging. Access options Buy single article. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. Triflic acid is manufactured by electrochemical fluorination of methanesulfonyl chloride or fluoride. Sulfenic acid formation in human serum albumin by hydrogen peroxide and peroxynitrite. Sulfenic acids are produced by the enzymatic decomposition of alliin and related compounds following tissue damage to garlic, onions, and other plants of the genus Allium. Published: 26 May 2020. Paper ID: NOV163864 … Photochemically Generated Thiyl Free Radicals Observed by X-ray Absorption Spectroscopy. Our results support the concept that sulfenic acid is a central intermediate in the formation of oxidized albumin species that … The reactions can generate dangerously large amounts of heat in small spaces. First insights into the mode of action of a “lachrymatory factor synthase” – Implications for the mechanism of lachrymator formation in Petiveria alliacea, Allium cepa and Nectaroscordum species. trans Sulfonic acids are strong acids. In addition, H 2 S is able to react with sulfenic acids (RSOH). You have to login with your ACS ID befor you can login with your Mendeley account. The nucleofugalities of a series of aliphatic carboxylates were determined for the first time by comparing the solvolysis rates of 4–X–4'–Y–benzhydryl carboxylates in a series of EtOH–H2O mixtures. Unexpected behavior of the reaction between acyl thioformanilides and acetonitrile derivatives—a useful entry to new penta-substituted dipyrrole disulfides. Palladium NPs supported on sulfonic acid functionalized metal–organic frameworks as catalysts for biomass cascade reactions† Xibo Zhang , a Luning Chen , a Yongjian Li , a Huiqi Li , a Zhaoxiong Xie , ab Qin Kuang * a and Lansun Zheng a Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Thamayanthy Sriskandakumar, Shirin Behyan, Abraha Habtemariam, Peter J. Sadler, and Pierre Kennepohl . -terphenylsilanes. Among the various methods used to prepare aliphatic sulfonic acids are the oxidation of other organosulfur compounds, the reaction of alkyl halides and metallic sulfites, and the reaction of organometallic compounds with amine complexes of sulfur trioxide (e.g., Me 3 NSO 3). Matteo Zecchini, Robert Lucas, Adam Le Gresley. & Account Managers, For

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